N-Diphenylphosphanyl-N-{[diphenyl(2-pyridylimino)-λ5-phosphanyl]methyl}pyridin-2-amine
نویسندگان
چکیده
In the title compound, C(35)H(30)N(4)P(2), the diphenyl-phosphanyl and diphen-yl(2-pyridyl-imino)-λ(5)-phosphanyl groups are attached to the central methyl C atom with a P-C-N angle of 114.09 (16)°. The mol-ecules stack along the b axis and inter-connect through C-H(pyrid-yl)⋯N(pyrid-yl) inter-actions, forming an infinite chain structure. The parallel chains are further inter-connected via C-H(benzene)⋯N(amino) and C-H(benzene)⋯π inter-actions, forming a three-dimensional framework.
منابع مشابه
1-[Phenyl(pyridin-2-ylamino)methyl]-2-naphthol
The title compound, C(22)H(18)N(2)O, was synthesized from naphthalen-2-ol, benzaldehyde and pyridin-2-amine. In the crystal, mol-ecules are linked into centrosymmetric R(2) (2)(16) dimers by pairs of O-H⋯N hydrogen bonds. The mol-ecular conformation is stabilized by an N-H⋯O hydrogen bond. The dihedral angle between the naphthylene ring system and the phenyl ring is 72.86 (12)°.
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